Author(s): Ali Kabli
Mentor(s): Pilgyu Kang, Mechanical Engineering
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Abstract
This project explores the potential for enhancing the performance of Laser-Induced Graphene (LIG) using metallic nanoparticles (NPs) as a platform for fabricating photosensors with enhanced sensitivity. The main question being addressed is can a Laser-Induced Graphene–Palladium nanoparticle (LIG-PdNP) nanocomposite enhance sensor sensitivity through plasmonic and interfacial effects? Research has been conducted in the past regarding the use of LIG as the functional material in a photosensor, and the rationalization behind using these metallic NPs in a nanocomposite material is to improve the sensitivity of the sensor by improving the photoresponsivity. This is due to the introduction of plasmonic effects from the NPs, which allows for the photocurrent to flow more efficiently. The main novelty behind this particular project’s approach lies in the synthesis of the nanocomposite, where classic means would have the NPs deposited on the LIG surface creating point contacts. The synthesis technique being explored here involved a one-step synthesis via precursors and a polymer substrate, which creates a “seamless interface” between the components of the functional material. This interface allows for the electrons to flow freely between the LIG and NPs, enhancing the photoresponsivity of the device. Two devices were compared, one with 0wt% of PdNPs, and another with 30wt% PdNPs in order to observe any improvements in the performance of the devices when hit with a blue laser (448.2nm wavelength). Future research regarding this project includes using NPs with higher plasmonic effects such as gold or silver, as well as refining the geometric footprint and patter of the sensor itself to increase performance further.
Audio Transcript
Hello everyone, my name is Ali Kabli and today I’m going to present to you my undergraduate research project, Laser Induced Graphene Nanoparticle Platforms for Plasmonic Enhanced Photosensing. This project was advised by Dr. Pilgyu Kang from the Department of Mechanical Engineering.
So to give a brief background and introduction, past research has been done by Dr. Kang and his group, utilizing laser-induced graphene, or LIG, as a sensing element in photosensors. Now, these sensors operate based on the premise of photosensitivity. You basically shine a laser of some known wavelength at the sensor, which will induce some photocurrent. The change in photocurrent can be observed and used for sensing purposes. We want to improve the sensitivity of these devices by introducing metallic nanoparticles, or NPs, to increase the plasmonic effects and photoresponsivity of these devices. Now, for the purposes of this project, the specific nanoparticles that were used were palladium. However, any metal that has known plasmonic effects can be used.
For the purposes of this presentation, or project, we proposed a novel nanocomposite synthesis technique, which resulted in a seamless interface between the LIG and the nanoparticles. Traditional methods would have you deposit these nanoparticles on the surface of the LIG, or whatever substrate you’re using, which results in a point contact between the particles and the bulk surface. The downside to this is the fact that that point contact doesn’t allow for the most efficient flow of electrons. However, through a one-step synthesis technique using precursors and polymer substrate, we are able to integrate these nanoparticles within the surface of the laser-induced graphene itself, allowing the electrons to flow seamlessly.
So, the main question that we were answering with this research project was, can a laser-induced graphene palladium nanoparticle nanocomposite enhance sensor sensitivity through plasmonic and interfacial effects? The plasmonic effects, once again, coming from the fact that we’re using these metallic nanoparticles, and the interfacial effects coming from the seamless interface through our unique synthesis technique.
The methods and procedure for this project involved the actual synthesis of our nanocomposite using the one-step technique. Then we would fabricate the photosensor device using the synthesized nanocomposite. It should be mentioned that the scale of this sensor was 500 millimeters by 500 milliliters, which is actually quite large given the nanoscale. It’s very, very large. So that may have resulted in the data being slightly skewed, which is an improvement that we will go over at the end of this presentation. Then we collected optical data regarding the photoresponsivity of the device by hooking it up to an optical testing apparatus where we would shine a laser on and off at known intervals. The laser’s wavelength was known for the purposes of this project. We were using a blue laser, 448.2 nanometers of wavelength, and we would plot the resulting photocurrent as a function of time. The long-term goals of this project are to one day harness these nanocomposites as a platform for plasmonically enhanced PEC or photoelectrochemical gas sensors.
Now here’s just a brief snapshot of the results. We see on the left side a comparison between the photocurrent resulting from a 30 weight percent nanoparticle nanocomposite and on the right side we have the photocurrent resulting from just pure LIG. As you can see the scale on the left side is in microamps, and the scale on the right side is in nanoamps, which means that we were able to show a drastic improvement, three orders of magnitude to be exact.
In conclusion, the experiment was a huge success in proving that plasmonic effects could enhance the sensitivity of these devices. However, more work is still needed in the future. We can refine the geometry and footprint of the sensor itself so that it’s a lot smaller than 500 by 500 millimeters. We can also test other nanoparticles with known greater plasmonic effects, such as gold or silver. And we can also play around with different laser parameters, focusing the laser’s beam more, increasing the wavelength, etc.
Some acknowledgements. Of course, my advisor, Dr. Pilgyu Kang, Graham Harper, who aided in data collection on this project, and Philip Acatrinei, for being an indispensable help in data collection and in setting up the experiment itself. He actually programmed the software that we were using to collect the data. So without him, this project would not have been possible. Thank you.